Let¡¯s face it, organic chemistry can seem difficult to learn. 126456-43-7. Especially from a beginner¡¯s point of view. Like 126456-43-7, Name is (1S,2R)-1-Amino-2,3-dihydro-1H-inden-2-ol. In a document type is Article, introducing its new discovery.
Circular dichroism sensing of chiral compounds using an achiral metal complex as probe
Coordination of a chiral substrate to (meso-salen)cobalt(II) nitrate and subsequent oxidation generates a Co(III) complex exhibiting a strong chiroptical readout that is attributed to spontaneous substrate-to-ligand chirality imprinting. The characteristic circular dichroism (CD) response of the (salen)cobalt complex can be used for enantiomeric analysis of a variety of chiral substrates based on a simple CD measurement at low concentration and without additional purification steps. This chirality sensing approach has potential for high-throughput enantiomeric excess (ee) screening applications and minimizes solvent waste production. Copyright
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Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis