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Disclosed herein are substituted diphenylmethyl picolinic acids, pharmaceutically acceptable salts, amides and esters thereof. The compounds disclosed are useful as topical anti-acne agents.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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A method is proposed for the synthesis of alpha-pyridyl ketones from acyl chlorides and 2-pyridylmethyl- and 4-pyridylmethylalanes.The prospects of the use of this method in the synthesis of C-pyridyl-substituted peracetylated uloses were demonstrated.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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The reaction of pyridine and methylpyridines with alpha, beta-unsaturated carboxylic acids, such as: acrylic, methacrylic, crotonic, cinnamic, itaconic, fumaric and maleic acid, as well as the reactions of di- and trimethylpyridines with acrylic and maleic acids were studied. The reactions developed by such compounds may be, actually, considered as a competition between addition and neutralization, resulting betaine and/or salt. The factors influencing the development reaction are the chemical structure of the amine, acid and solvent, as well as the reaction duration. The order of reactivity for the same reactions was established by half-times. The 1H-NMR methodology was applied for elucidating both the chemically obtained structures and the half-times.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. Electric Literature of 31886-57-4, Name is (S)-N,N-Dimethyl-1-ferrocenylethylamine, belongs to chiral-nitrogen-ligands compound, is a common compound. Electric Literature of 31886-57-4Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. In an article, authors is , once mentioned the new application about Electric Literature of 31886-57-4.

A functionalized magnetic nanoparticle including an organometallic sandwich compound and a magnetic metal oxide. The functionalized magnetic nanoparticle may be reacted with a metal precursor to form a catalyst for various C?C bond forming reactions. The catalyst may be recovered with ease by attracting the catalyst with a magnet.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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Having gained chemical understanding at molecular level, Safety of (S)-N,N-Dimethyl-1-ferrocenylethylamine, Name is (S)-N,N-Dimethyl-1-ferrocenylethylamine, belongs to chiral-nitrogen-ligands compound, is a common compound. Safety of (S)-N,N-Dimethyl-1-ferrocenylethylamine chemistry graduates may choose to apply this knowledge in almost unlimited ways, as it can be used to analyze all matter and therefore our entire environment. In an article, authors is Ori, Aiichiro, once mentioned the new application about Safety of (S)-N,N-Dimethyl-1-ferrocenylethylamine.

A chiral ferrocenylboronic acid 1 bearing an intramolecular tertiary amine binds saccharides at ca. pH 7, the complexation event, which can be conveniently detected by an electrochemical method, shows chiral discrimination for certain linear saccharides.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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Compounds and related methods for inhibition of mammalian and bacterial nitric oxide synthase.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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Molybdenum hexacarbonyl reacts with 2,4-dimethylpyridine, 3-butylpyridine or 4-methylquinoline in refluxing acetonitrile to give the respective ligand complexes [Mo(CO)4(2,4-Me2py)2], [Mo(CO)5(3-Bupy)] and [Mo(CO)5(4-methylquinoline)]. The complexes have been characterized by IR, PMR, mass spectra and elemental analysis.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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The ion mobility techniques, including the most commonly used drift-tube ion mobility spectrometry (IMS) and differential mobility spectrometry (DMS), are used successfully for the detection of a wide range of organic compounds in the gas phase. In order to improve detection quality, admixtures are added to gas streams flowing through the detector. Dopants mostly prevent the ionization of interfering chemicals however, better detection may be also achieved by shifting the peaks in the drift-time spectra, enabling ionization of analytes with low proton affinities and, thus, facilitating photoionization. Fundamental information about ion-molecule reactions including the role of dopants is presented. The term ‘gas modifiers’ refers to substances that influence the ion transport by changing the mobility of ions without changing the chemistry of the ionization. The mechanism of the gas modifier’s interaction with an analyte in ion separation in drift tube IMS and DMS is explained in this paper.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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Either ZnCl2, Sc(OTf)3, or BF3OEt 2 can promote the palladium-catalyzed arylation of methylpyridines and related heterocycles (see example). The complexation of the Lewis acid to the nitrogen atom in the heterocycle facilitates the reductive elimination, leading to various arylated pyridines in high yields. BF3OEt 2 was also found to promote highly regioselective metalations in the case of 2,4-lutidine. Copyright

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

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The present invention relates to compounds of general formula (II),to compositions comprising these compounds and to methods of treating Enterobacteriaceae bacterial diseases and infections using the compounds. The compounds find application in the treatment of infection with, and diseases caused by, Enterobacteriaceae.

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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis