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Polynuclear Co(II) Myrtenates with 2,4-Lutidine
Abstract: The reaction of cobalt(II) chloride with potassium myrtenate (KMyr) followed by addition of 2,3-lutidine in ethanol gives the trinuclear compound [Co3(Myr)6(2,4-Lut)2] (I). The central cobalt(II) atom is linked to each of the two other metal atoms by three myrtenic acid anions. The reaction of a solution of compound I with lithium myrtenate (LiMyr) results in the formation of tetranuclear heterometallic complex [Li2-Co2(Myr)6(2,4-Lut)2] (II). Compound II is composed of two binuclear {LiCo(Myr)3(2,4-Lut)} moieties, in which the lithium(I) atoms are linked to cobalt(II) atoms by bridging myrtenate anions. The lithium atoms are connected by two oxygen atoms of acid anions. Compounds I and II were characterized by X-ray diffraction (CIF files CCDC nos. 1898096 (I), 1898097 (II)).
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Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis