A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Recommanded Product: Potassium hexadecyl hydrogenphosphate, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 19035-79-1, Name is Potassium hexadecyl hydrogenphosphate, molecular formula is C16H34KO4P. In an article, author is Talele, Harish R.,once mentioned of 19035-79-1.
Diquats with Robust Chirality: Facile Resolution, Synthesis of Chiral Dyes, and Application as Selectors in Chiral Analysis
Diquats with extremely high racemization barriers with G(theor) of 233kJmol(-1) at 180 degrees C are described. Reported configurational robustness is due to a combination of two structural features: the rigid o-xylylene tether connecting the nitrogen atoms and the presence of two substituents in the bay region of the bipyridinium scaffold. The straightforward synthesis of diquats, plus facile resolution and derivatization make them attractive for chiral application studies. This is demonstrated by: 1)synthesis of the first non-racemic diquat dyes with pronounced chiroptical properties, and 2)capability of diquats to interact stereospecifically with chiral molecules. This suggests potential for diquat derivatives to be used as chiral selectors in separation methods.
If you¡¯re interested in learning more about 19035-79-1. The above is the message from the blog manager. Recommanded Product: Potassium hexadecyl hydrogenphosphate.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis