In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. 108-47-4, Name is 2,4-Dimethylpyridine, belongs to chiral-nitrogen-ligands compound, is a common compound. 108-47-4Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. In an article, authors is Ilczyszyn, Marek, once mentioned the new application about 108-47-4.
At moderately low temperatures, 293-213 K, phenols and pyridines form complexes linked by hydrogen bridges as a way for proton migration: A-H…B –>/<-- A(1-)...H-B(1+).The enthalpy and entropy variations induced by this intracomplex proton transfer have been evaluated for the 2,6-dichloro-4-nitrophenol-3,5-lutidine complex from the temperature dependences of the phenol 13C chemical shifts.At lower temperatures, down to 110 K, 1H NMR results provided direct evidence for the homoconjugation equilibrium: A(1-)...H-B(1+) + B -->/<-- (A(1-))(B2-H(1+)).Separate 1H signals of the B-H(1+) and B2-H(1+) species were recorded for solutions of pyridines with thiophenol, trifluoroacetic acid or methanesulfonic acid with molar excess of the base.The hydrogen-bridge protons in the homoconjugated cations were strongly deshielded, at ca. 20.5 ppm, and this observation suggests their central or near-central position in the bonds: delta+B...H...Bdelta+.The thermodynamic quantities of the homoconjugation equilibrium were calculated for selected systems. Future efforts will undeniably focus on the diversification of the new catalytic transformations. These may comprise an expansion of the substrate scope from aromatic and heteroaromatic compounds to other hydrocarbons. 108-47-4, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 108-47-4, in my other articles.
Reference：
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis