The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 5-(4-Pyridyl)-1H-tetrazole(SMILESS: C1(C2=NN=NN2)=CC=NC=C1,cas:14389-12-9) is researched.Safety of 2-(7-Bromo-1H-indol-3-yl)acetic acid. The article 《Secondary spacer modulated assembly of polyoxometalate based metal-organic frameworks》 in relation to this compound, is published in Dalton Transactions. Let’s take a look at the latest research on this compound (cas:14389-12-9).
To study the influence of a secondary spacer on the resulting structures of POMOFs containing pytz, five new compounds with different dimensionalities, [Cu5(2-pytz)6(H2O)4][SiMo12O40]·3H2O (1), [Cu3(2-pytz)4bipy][H2SiMo12O40]·bipy (2), [Cu3(2-pytz)2(bipy)4(H2O)6][H4SiW12O40]2·6H2O (3), [Cu2(2-pytz)(phen)(OH)]2[SiW12O40]·H2O (4), [Cu3(4-pytz)4(H2O)4][H2SiW12O40]·2H2O (5) (pytz = pyridyltetrazole), were synthesized. When only 2-pytz was employed, compound 1 with a 3D framework was obtained, whereas when the secondary spacers (4,4′-bipy, phen and 4-pytz) were introduced into the reaction system of 1, compounds 2-5 were obtained and exhibit a broad range of structures, including 0D, 1D, 2D and 3D frameworks. It can be observed from the architectures of compounds 1-5 that the secondary spacers have a great effect on the structures of the MOFs, which gave various dimensional POMOF compounds Addnl., photocatalytic experiments of 1-5 for the photocatalytic degradation of RhB under UV irradiation were also studied.
This literature about this compound(14389-12-9)Application In Synthesis of 5-(4-Pyridyl)-1H-tetrazolehas given us a lot of inspiration, and I hope that the research on this compound(5-(4-Pyridyl)-1H-tetrazole) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis