The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 5-(4-Pyridyl)-1H-tetrazole(SMILESS: C1(C2=NN=NN2)=CC=NC=C1,cas:14389-12-9) is researched.Product Details of 707-61-9. The article 《Porous Nitrogen Rich Cadmium-Tetrazolate Based Metal Organic Framework (MOF) for H2 and CO2 Uptake》 in relation to this compound, is published in Crystal Growth & Design. Let’s take a look at the latest research on this compound (cas:14389-12-9).
The highly porous nitrogen rich metal organic framework [Cd3(4-TP)6] (Cd-4TP-1) was synthesized solvothermally from the predesigned organic building block 4-tetrazole pyridine (4-TP) and Cd(II) as metal center using DMF as solvent. Cd-4TP-1 has a three-dimensional porous architecture where all the binding sites of Cd(II) are exclusively occupied by the nitrogen atoms from the μ2-tetrazolyl group or the pyridyl functionality of the 4-TP ligands. Cd-4TP-1 has Brunauer-Emmett-Teller (BET) and Langmuir surface areas of 472.2 and 728.6 m2/g, resp., and shows 1.1% H2 (77 K) and 2.7 mmol/g CO2 uptake (273 K).
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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis