Chemistry is traditionally divided into organic and inorganic chemistry. name: 2,4-Dimethylpyridine, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 108-47-4
Reaction of Dimeric Copper(II) Acetate with Pyridine and Quinoline Bases in Dioxane
Copper(II) acetate reacts with pyridine and quinoline bases in dioxane giving rise to adduct compounds, which were characterized by UV and EPR techniques.The reaction is formulated as follows: Cu2(OAc)4+L<*>Cu2(OAc)HL, where L denotes a free base and K21 is an adduct formation constant.Values of K21 range from 12 for quinoline or 2-picoline to 146 mol-1 dm-3 for 4-ethylpyridine.A linear free energy relationship is observed between the adduct formation and the protonation of bases in water except for sterically crowded bases.
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Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis