Chemistry is an experimental science, Safety of 2-Methyltetrahydrofuran, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 96-47-9, Name is 2-Methyltetrahydrofuran, molecular formula is C5H10O, belongs to chiral-nitrogen-ligands compound. In a document, author is Zhang Yongna.
Research Progress in Asymmetric Reactions of Imines Using Chiral Primary Amines as Organocatalysts
Chiral primary amine is a kind of important small organic molecule catalyst in the field of asymmetric organocatalysis. Like secondary amine catalyst, primary amine can react with carbonyl compounds to form reactive intermediate of enamine or iminium to catalyze various asymmetric reactions, achieving excellent enantioselectivities. The catalytic asymmetric 1,2-addition to the electrophilic C=N double bond of imines (involving imine intermediates in the reaction process) is the most efficient way to obtain nitrogen-containing compounds bearing alpha-chiral center. In recent years, the highly enantioselective asymmetric reaction of imines by chiral primary amine catalysts has made some progress, so this topic is summarized and prospected.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 96-47-9. Safety of 2-Methyltetrahydrofuran.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis