A new application about 3388-04-3

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 3388-04-3. Recommanded Product: Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane.

Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 3388-04-3, Name is Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane, molecular formula is C11H22O4Si, belongs to chiral-nitrogen-ligands compound. In a document, author is Jolley, Katherine E., introduce the new discover, Recommanded Product: Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane.

A general and atom-efficient continuous-flow approach to prepare amines, amides and imines via reactive N-chloramines

Chloramines are an important class of reagents, providing a convenient source of chlorine or electrophilic nitrogen. However, the instability of these compounds is a problem which makes their isolation and handling difficult. To overcome these hazards, a continuous-flow approach is reported which generates and immediately reacts N-chloramines directly, avoiding purification and isolation steps. 2-Chloramines were produced from the reaction of styrenes with N-alkyl-N-sulfonyl-N-chloramines, whilst N-alkyl or N,N’-dialkyl-N-chloramines reacted with anisaldehyde in the presence of t-BuO2H oxidant to afford amides. Primary and secondary imines were produced under continuous conditions from the reaction of N-chloramines with base, with one example subsequently reduced under asymmetric conditions to produce a chiral amine in 94% ee.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 3388-04-3. Recommanded Product: Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis