In an article, author is Fukumoto, Yoshiya, once mentioned the application of 2344-80-1, Recommanded Product: (Chloromethyl)trimethylsilane, Name is (Chloromethyl)trimethylsilane, molecular formula is C4H11ClSi, molecular weight is 122.6686, MDL number is MFCD00000878, category is chiral-nitrogen-ligands. Now introduce a scientific discovery about this category.
A New Class of Redox Isomerization of N-Alkylpropargylamines into N-Alkylideneallylamines Catalyzed by a ReBr(CO)(5)/Amine N-oxide System
Redox isomerization reaction wherein N-alkylpropargylamines are converted into N-alkylideneallylamines in the presence of rhenium(I) complexes as catalysts is described. Among the additives tested, certain pyridine N-oxides and tertiary amine N-oxides were effective for the reaction to proceed, and in particular, the use of 2,6-lutidine N-oxides gave the best results. The choice of a diphenylmethyl group as a substituent on the nitrogen atom was key to the success of the reaction, allowing it to reach completion.
If you are interested in 2344-80-1, you can contact me at any time and look forward to more communication. Recommanded Product: (Chloromethyl)trimethylsilane.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis