Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 14389-12-9, is researched, Molecular C6H5N5, about Syntheses Study of Keggin POM Supporting MOFs System, the main research direction is preparation silver pyridyltetrazolate molybdate tungstate Keggin MOF; crystal structure silver pyridyltetrazolate molybdate tungstate Keggin MOF; luminescence silver pyridyltetrazolate molybdate tungstate Keggin MOF.Reference of 5-(4-Pyridyl)-1H-tetrazole.
To study the influence of reactive conditions on the structures of Keggin POM supporting metal-organic frameworks (MOFs), five new compounds, [Ag6(2-pytz)4(H2O)2][HPMo12O40] (1), {[Ag14(2-pytz)12(H2O)4][H2PMo12O40]2}·3H2O (2), {[Ag6(2-pytz)4(H2O)4][H2SiW12O40]}·6H2O (3), {[Ag3(3-pytz)2]2·[AgPMo12O40]}·2H2O (4), [Ag6(4-pytz)4][HPMo12O40] (5) [pytz = 5-(pyridyl)tetrazolate], were hydrothermally synthesized by tuning the reactive species and pH values and characterized by routine method and single-crystal x-ray crystallog. Although compounds 1-5 all show the POM supporting 3-dimensional MOFs skeleton, MOFs exhibit diverse structures and POMs play different supporting functions, more specifically, pseudo POM chains supporting MOFs in 1 and 2, isolated POM spheres supporting MOFs in 3, true POM chains supporting MOFs in 4, and pseudo POM layers supporting MOFs in 5. The roles of the pH value, pytz derivatives, and the Keggin homologs in the formation of the POM supporting MOFs are discussed. The photoluminescence properties of compounds 1-3 were studied in the solid state at room temperature
This literature about this compound(14389-12-9)Reference of 5-(4-Pyridyl)-1H-tetrazolehas given us a lot of inspiration, and I hope that the research on this compound(5-(4-Pyridyl)-1H-tetrazole) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis