Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 96-47-9, Name is 2-Methyltetrahydrofuran, molecular formula is C5H10O, belongs to chiral-nitrogen-ligands compound, is a common compound. In a patnet, author is Gross, Cedric, once mentioned the new application about 96-47-9, Application In Synthesis of 2-Methyltetrahydrofuran.
Iron(II) Complexes of Chiral Tridentate Nitrogen Donors and their Application in Catalytic Hydrosilylation Reactions
Enantiomerically pure, C-2-symmetric 2,6-bis(pyrazol-3-yl) pyridine ligands were obtained by treatment of diethyl-2,6-pyridinedicarbonate with (1R,4R)-(+)-camphor in the presence of NaH followed by ring closure with hydrazine. After twofold N-alkylation at the pyrazole rings, the addition of iron(II) chloride led to the according pentacoordinate dichloridoiron(II) complexes. All intermediates of the ligand synthesis, the ligands bearing NCH3 and NCH2C6H5 groups and the derived iron(II) complexes were structurally characterized by means of X-ray structure analysis. In-situ reaction with iron(II) carboxylates resulted in the formation of iron(II) carboxylate complexes, which turned out to be highly active in the hydrosilylation of acetophenone. However, even at room temperature, the enantiomeric excess of the product 1-phenylethanol is poor. Fe-57 Mossbauer spectroscopy gave an insight into the species formed during catalysis.
We¡¯ll also look at important developments in the pharmaceutical industry because understanding organic chemistry is important in understanding health, medicine, 96-47-9. The above is the message from the blog manager. Application In Synthesis of 2-Methyltetrahydrofuran.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis