The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. SDS of cas: 96-47-9, 96-47-9, Name is 2-Methyltetrahydrofuran, SMILES is CC1OCCC1, in an article , author is Han, Jianlin, once mentioned of 96-47-9.
Chromatographic approach to study the configurational stability of Ni(II) complexes of amino-acid Schiff bases possessing stereogenic nitrogen
Herein, we disclose the design of a model Ni(II) complex of glycine Schiff base possessing single-nitrogen stereogenic center, which was successfully used for high-performance liquid chromatography (HPLC)-assisted assessment of its configurational stability. The major finding is that the configurational stability of the Ni(II)-coordinated nitrogen is profoundly dependent on the reaction conditions used, in particular the solvent, and can range from inconsequential (t(1/2) less than 5 min) to virtually completely stable (t(1/2) 90 y). The discovery reported in this study most likely to be of certain theoretical and synthetic value.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 96-47-9, you can contact me at any time and look forward to more communication. SDS of cas: 96-47-9.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis