937-30-4, Name is 4-Ethylacetophenone, molecular formula is C10H12O, Formula: C10H12O, belongs to chiral-nitrogen-ligands compound, is a common compound. In a patnet, author is Liu, Zheyuan, once mentioned the new application about 937-30-4.
DFT Mechanistic Account for the Site Selectivity of Electron-Rich C(sp(3))-H Bond in the Manganese-Catalyzed Aminations
DFT study suggests that the C-H cleavage involved in the C(sp(3))-H amination catalyzed by manganese perchlorophthalocyanine complex [Mn-III(ClPc)](+) proceeds via hydride transfer (HYT), instead of hydrogen atom transfer (HAT), thus elucidating why the reaction favors aminating the electron-rich C-H bond, rather than that with smaller bond dissociation energy preferred by HAT. Detailed analyses indicate the HYT actually occurs via concerted electron and hydrogen atom transfers and the redox-active ClPc ligand enables the HYT.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 937-30-4 help many people in the next few years. Formula: C10H12O.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis