Synthetic Route of 31886-57-4, Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.31886-57-4, Name is (S)-N,N-Dimethyl-1-ferrocenylethylamine, molecular formula is C14H19FeN. In a article£¬once mentioned of 31886-57-4
One-pot alpha-ferrocenylalkylation of amines and alcohols with alpha-ferrocenyl substituted alcohols under acid-free conditions
One-pot reaction of FcCH(R)OH with equimolar quantities of BunLi and EtOCOCl followed by an excess of amine produces N-(alpha-ferrocenylalkyl)amines in up to 98% yields. Nitrogen heteroaryl amines undergo the alpha-ferrocenylalkylation at the amino group. The alpha-ferrocenylalkylation of alcohols and phenols (R’OH) leads to a formation of ethers FcCH(R)OR? in lower yields. The reactions proceed via an intermediate formation of alpha-ferrocenylalkyl carbonates FcCH(R)OCOOEt. The side reactions associated with this protocol are discussed.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction. the role of 31886-57-4, and how the biochemistry of the body works.Synthetic Route of 31886-57-4
Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis