Synthetic Route of C30H21P. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Tri(naphthalen-1-yl)phosphine, is researched, Molecular C30H21P, CAS is 3411-48-1, about The hydroformylation of conjugated dienes. VI. Tertiary aryl- and arylalkylphosphines and secondary alkyl- and arylphosphines as ligands in the rhodium-catalyzed hydroformylation reaction of conjugated dienes to dialdehydes. Author is Bahrmann, H.; Fell, B..
The dependence of the formation of products and isomers on the phosphine used was studied in the title Rh-catalyzed hydroformylation of 1,3-butadiene to dialdehydes. Product formation is directed by a complex combination of steric and electronic factors in the tertiary phosphines. Secondary phosphines are also good cocatalysts for the hydroformylation of butadiene. They lead to an almost complete 1,4-hydroformyl-addition route to the 1,3-diene in the primary step of the hydroformylation of conjugated dienes.
In addition to the literature in the link below, there is a lot of literature about this compound(Tri(naphthalen-1-yl)phosphine)Synthetic Route of C30H21P, illustrating the importance and wide applicability of this compound(3411-48-1).
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis