Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, the author is Estivill, Carla and a compound is mentioned, 126456-43-7, (1S,2R)-1-Amino-2,3-dihydro-1H-inden-2-ol, introducing its new discovery. 126456-43-7
The bidentate complexes of (R,R)- and meso-alpha,alpha?- bis(trifluoromethyl)-9,10-anthracenedimethanol with cis-1-amino-2-indanol
The enantiorecognition of 1-aminoindane 3 and cis-1-amino-2-indanol 2 by (R,R)-alpha,alpha?-bis(trifluoromethyl)-9,10-anthracenedimethanol 1 is reported. The examination of the bidentate associations between 1 and 2 revealed that the cisoid conformation of 1 is responsible for the separation of the NMR signals. Two types of bimodal associations resulted from a cisoid conformation when meso-1 isomer was tested. Molecular mechanics modelling studies gave the possible structures of the associate species.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! Read on for other articles about 5391-39-9!, 126456-43-7
Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis