Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , SDS of cas: 96-47-9, 96-47-9, Name is 2-Methyltetrahydrofuran, molecular formula is C5H10O, belongs to chiral-nitrogen-ligands compound. In a document, author is Li, Quan-Wei, introduce the new discover.
Palladium/Copper-Mediated Switchable Approaches towards (Chloro)ethenylphosphorylamides by Phosphorylamides and Alkenes
A switchable access to ethenylphosphorylamides and chloroethenylphosphorylamides from phosphorylamides and alkenes has been disclosed herein. With the assistance of Pd(OAc)(2), a catalytic loading of CuCl2 or CuBr (20 mol-%) led to the occurrence of dehydrogenative cross coupling reactions with high efficiency and broad substrate scope, while 1.0 equivalent of CuCl2 rendered the dehydrogenative amidochlorination reactions to take place with high stereoselectivity.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 96-47-9. SDS of cas: 96-47-9.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis