Category: 14389-12-9

Recommanded Product: 14389-12-9. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Crystal structure of tetraaquabis(4-(5-tetrazolato)pyridyl-N)copper(II) tetrahydrate, Cu(H2O)4(C6H4N5)2·4H2O. Author is Wang, Ji-Wu; Guo, Jin-Xin; Fu, Feng; Li, Dong-Sheng; Wang, Ji-Jiang; Zhang, Mei-Li.

Crystallog. data and at. coordinates are given. The copper atom is coordinated in a distorted octahedral manner and trans-connected to two 4-PTZ anions [d(Cu-N) = 2.034(4) Å] and four mols. of water [d(Cu-O1) = 1.947(4), d(Cu-02) = 2.482(4) Å]. The remaining four water mols. act as lattice water mols. Within the equatorial plane, the sum of the bond angles around the Cu atom is 360 °. The apical O2-Cu-O2′ bond angle is 180 °. In the supramol. complex, the eight water mols. and the noncoordinating N atoms of the tetrazolato ligands form an extensive H-bonding system. All the water form strong H bonds between themselves or with the noncoordinating N atoms of the tetrazolato ligands occur strong H bonds. So, a two-dimensional network structure is constructed by hydrogen bonding interactions. Moreover, a three-dimensional network structure is formed by the face-to-face π-π interactions of the pyridine ring and the tetrazolate ring ligands belonging to adjacent dimeric units with distances of about 3.45 Å.

Different reactions of this compound(5-(4-Pyridyl)-1H-tetrazole)Recommanded Product: 14389-12-9 require different conditions, so the reaction conditions are very important.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Safety of 5-(4-Pyridyl)-1H-tetrazole. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about 5-(Pyridinium-4-yl)-1H-1,2,3,4-tetrazol-1-ide. Author is Xu, Qian; Xu, Jie.

In the title zwitterionic mol., C6H5N5, the tetrazole and pyridine rings are nearly coplanar, making a dihedral angle of 2.08(1)°. In the crystal, mols. are connected by classical N-H…N and weak C-H…N H bonds. Crystallog. data and at. coordinates are given.

The article 《5-(Pyridinium-4-yl)-1H-1,2,3,4-tetrazol-1-ide》 also mentions many details about this compound(14389-12-9)Safety of 5-(4-Pyridyl)-1H-tetrazole, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 5-(4-Pyridyl)-1H-tetrazole( cas:14389-12-9 ) is researched.Safety of 5-(4-Pyridyl)-1H-tetrazole.Pellizzeri, Steven; Delaney, Sean P.; Korter, Timothy M.; Zubieta, Jon published the article 《Using Terahertz Spectroscopy and Solid-State Density Functional Theory to Characterize a New Polymorph of 5-(4-pyridyl)tetrazole》 about this compound( cas:14389-12-9 ) in Journal of Physical Chemistry A. Keywords: terahertz spectroscopy solid DFT crystallog characterize polymorph pyridyltetrazole. Let’s learn more about this compound (cas:14389-12-9).

A new high-temperature polymorph of 5-(4-pyridyl)tetrazole was discovered and characterized using x-ray crystallog. and terahertz (THz) spectroscopy. The THz spectrum of the new polymorph was compared to the previously published form and was replicated by solid-state d. functional theory. Terahertz spectroscopy was used to determine the influence of the different packing motifs on the mol. and low energy lattice vibrations displayed at 10-100 cm-1. There is only a ∼ 2 cm-1 difference in the primary peak location, caused by a whole mol. rotation along the principal a axis, between the two polymorphic forms. The energy of formation was determined, and the previously known polymorphic form is more stable by ∼0.25 kJ/mol, compared to the newly discovered form.

Different reactions of this compound(5-(4-Pyridyl)-1H-tetrazole)Safety of 5-(4-Pyridyl)-1H-tetrazole require different conditions, so the reaction conditions are very important.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 14389-12-9, is researched, SMILESS is C1(C2=NN=NN2)=CC=NC=C1, Molecular C6H5N5Journal, Article, Acta Crystallographica, Section E: Structure Reports Online called Triaquadichlorido[5-(4-pyridinio)tetrazolato-κN2]cobalt(II) monohydrate, Author is Wang, Bo, the main research direction is crystal structure cobalt pyridinio tetrazolato chloro aqua complex monohydrate; mol structure cobalt pyridiniotetrazolato chloro aqua complex hydrate; hydrogen bond cobalt pyridiniotetrazolato chloro aqua complex monohydrate; pi stacking cobalt pyridiniotetrazolato chloro aqua complex monohydrate; tetrazolato pyridinio cobalt chloro aqua monohydrate crystal mol structure.SDS of cas: 14389-12-9.

Triaquadichloro[5-(4-pyridinio)tetrazolato-κN2]cobalt monohydrate, [CoCl2(C6H5N5)(H2O)3]·H2O, was synthesized by hydrothermal reaction of CoCl2 with 4-(2H-tetrazol-5-yl)pyridine. The CoII cation is coordinated by 2 Cl- ions, 1 N atom from the 5-(4-pyridinio)tetrazolate zwitterion and 3 O atoms from 3 H2O mols. in a distorted octahedral geometry. In the crystal, mols. are linked into a 3-dimensional network by N-H···Cl H bonds and O-H···O/N/Cl H bonds involving both coordinated and uncoordinated H2O mols. Strong π-π stacking is present between parallel pyridinium and tetrazolate rings [centroid-centroid distances = 3.411(2) and 3.436(2) Å]. Crystallog. data are given.

The article 《Triaquadichlorido[5-(4-pyridinio)tetrazolato-κN2]cobalt(II) monohydrate》 also mentions many details about this compound(14389-12-9)SDS of cas: 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Product Details of 14389-12-9. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Zinc chloride-catalyzed synthesis of 5-substituted 1H-tetrazoles under solvent free condition. Author is Rostamizadeh, Shahnaz; Ghaieni, Hamid; Aryan, Reza; Amani, Ali.

Zinc chloride is an efficient and safe catalyst in the [3 + 2] cycloaddition reaction of organic nitriles with sodium azide in solventless condition. The corresponding 5-substituted 1H tetrazoles were obtained under mild conditions. This method can overcome disadvantages such as: the use of toxic metals and expensive reagents, drastic reaction conditions, water sensitivity and the presence of dangerous hydrazoic acid.

The article 《Zinc chloride-catalyzed synthesis of 5-substituted 1H-tetrazoles under solvent free condition》 also mentions many details about this compound(14389-12-9)Product Details of 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Category: chiral-nitrogen-ligands. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Expanded perlite: an inexpensive natural efficient heterogeneous catalyst for the green and highly accelerated solvent-free synthesis of 5-substituted-1H-tetrazoles using [bmim]N3 and nitriles. Author is Jahanshahi, Roya; Akhlaghinia, Batool.

A versatile, green and highly accelerated protocol for preparing 5-substituted-1H-tetrazoles was reported. In this method, 5-substituted-1H-tetrazoles were synthesized from nitriles and [bmim]N3, in the presence of the expanded perlite as an inexpensive natural efficient heterogeneous catalyst, under solvent-free condition. A wide variety of aryl nitriles underwent [3+2] cycloaddition to afford the desired tetrazoles in good to excellent yields, rapidly. This method had the advantages of high yields, short reaction times, simple methodol. and easy work-up. The catalyst was recovered by simple filtration and reused delivering good yields.

The article 《Expanded perlite: an inexpensive natural efficient heterogeneous catalyst for the green and highly accelerated solvent-free synthesis of 5-substituted-1H-tetrazoles using [bmim]N3 and nitriles》 also mentions many details about this compound(14389-12-9)Category: chiral-nitrogen-ligands, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Wang, Fei; Zhang, Jian; Yu, Rongmin; Chen, Shu-Mei; Wu, Xiao-Yuan; Chen, Shan-Ci; Xie, Yi-Ming; Zhou, Wei-Wei; Lu, Can-Zhong published the article 《Topological derivation from centrosymmetry to noncentrosymmetry in a three-dimensional polar framework material》. Keywords: copper bromo pyridyltetrazole polymeric complex preparation SHG.They researched the compound: 5-(4-Pyridyl)-1H-tetrazole( cas:14389-12-9 ).SDS of cas: 14389-12-9. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:14389-12-9) here.

Strong second harmonic generation (SHG) response was presented by a three-dimensional polar framework material [Cu2(L)Br]n (1; HL = 5-(4-pyridyl)tetrazole), which was obtained by reacting CuBr with HL under solvothermal conditions and displayed an noncentrosym. (3,4)-connected topol. derived from the centrosym. CdSO4 net.

The article 《Topological derivation from centrosymmetry to noncentrosymmetry in a three-dimensional polar framework material》 also mentions many details about this compound(14389-12-9)SDS of cas: 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Product Details of 14389-12-9. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Hydrothermal Preparation of Novel Cd(II) Coordination Polymers Employing 5-(4-Pyridyl)tetrazolate as a Bridging Ligand. Author is Xue, Xiang; Wang, Xi-Sen; Wang, Li-Zhong; Xiong, Ren-Gen; Abrahams, Brendan F.; You, Xiao-Zeng; Xue, Zi-Ling; Che, Chi-Ming.

The reaction of 4-cyanopyridine with NaN3 in the presence of H2O and a Lewis acid (CdCl2) affords a novel 3-dimensional pillared-layered fluorescent and phosphorescent coordination polymer Cd3(OH)2Cl2(4-PTZ)2 (4-PTZ = 5-(4-pyridyl)tetrazolate) (1) while the direct reaction of CdCl2 with H-PTZ gives the simpler species Cd(4-PTZ)2(H2O)2. The solid-state structure and nature of 1 provide an indication of the type of materials that may be formed as intermediates in the Sharpless-Demko reaction for the generation of 5-substituted 1H-tetrazoles.

The article 《Hydrothermal Preparation of Novel Cd(II) Coordination Polymers Employing 5-(4-Pyridyl)tetrazolate as a Bridging Ligand》 also mentions many details about this compound(14389-12-9)Product Details of 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Application of 14389-12-9. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Synthesis, structures and characterization of two mononuclear Ru(III)-edta complexes. Author is Kuang, Wei-wei; Yang, Pei-pei.

Two ruthenium (III) complexes containing ethylenediaminetetraacetate (EDTA), [Ru(Hedta)(4-ptz)].4H2O (1) and [Ru(Hedta)(2,5-Pydc)]·3H2O (2), were synthesized by the K[Ru(Hedta)Cl]·1.5H2O reacting with 5-(4-pyridyl)tetrazole (4-ptz) or 2,5-pyridinedicarboxylic acid (2,5-Pydc) in water solution Complex 1 crystallized in monoclinic system, space group C2/c with a 2.34806(15), b 1.30123(8), c 1.49308(9) nm, β 101.0750(10)°. Complex 2 crystallizes in monoclinic system, space group I2/a with a 3.2494(7), b 0.96623(19), c 1.4341(3) nm, β 93.88(3)°. The products were characterized by IR and UV-visible. Their DNA-binding activities were studied using electronic absorption spectroscopic methods and fluorescence quenching; these two ruthenium complexes may bind to CT-DNA through intercalation modes.

After consulting a lot of data, we found that this compound(14389-12-9)Application of 14389-12-9 can be used in many types of reactions. And in most cases, this compound has more advantages.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 14389-12-9, is researched, SMILESS is C1(C2=NN=NN2)=CC=NC=C1, Molecular C6H5N5Journal, Article, Research Support, Non-U.S. Gov’t, Dalton Transactions called Constructing novel Cd(II) metal-organic frameworks based on different highly connected secondary building units via alteration of reaction conditions, Author is Liu, Yan-Qing; Ren, Guo-Jian; Zhang, Ying-Hui; Xu, Jian; Bu, Xian-He, the main research direction is cadmium pyridyltetrazolate MOF preparation crystal structure photoluminescence; thermal decomposition gas adsorption cadmium pyridyltetrazolate MOF.Related Products of 14389-12-9.

Upon solvothermal reactions between Cd(II) salt and 5-pyridyl-tetrazolate (4-Ptz) under different reaction conditions, three new Cd(II) metal-organic frameworks (MOFs), namely [Cd3(4-Ptz)5(H2O)2(μ3-OH)·3DMA·5H2O·CH3OH]n (1), [Cd5(4-Ptz)8(CH3OH)2(μ3-OH)2·2DMA·4H2O·3CH3OH]n (2) and [{Cd9(4-Ptz)14(AC)2(μ3-OH)2(H2O)4}·8DMA·H2O·3CH3OH]n (3), were synthesized based on different highly connected secondary building units (SBUs). In the presence of triethylamine, 1 was constructed based on an 8-connected triangular trinuclear Cd3 SBU and exhibits a three-dimensional framework, while 2 was generated upon the addition of HCl, assembled through a close packing of the octahedron cages consisting of unprecedented 12-connected 4-Ptz bridged Cd5 SBUs and thus showing high thermal and chem. stability. For generating 3, two different kinds of Cd3 SBUs, including an 8-connected triangular SBU and a 10-connected linear SBU, were constructed and further integrated into a distorted octahedron-based net under the addition of both triethylamine and NaCl. In addition to the structural anal., the authors also focused on the investigation of gas adsorption and solid-state fluorescence properties of 2.

After consulting a lot of data, we found that this compound(14389-12-9)Related Products of 14389-12-9 can be used in many types of reactions. And in most cases, this compound has more advantages.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis