Application of 31886-57-4, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 31886-57-4, (S)-N,N-Dimethyl-1-ferrocenylethylamine, introducing its new discovery.
FERROCENYLTRITHIOCARBONATES I. DIRECT ACCESS FROM alpha-FERROCENYLCARBINOLS BY A SNi MECHANISM. ABSOLUTE X-RAY STRUCTURE DETERMINATION OF (R)-FERROCENYLMETHYLMETHANE S-METHYLTRITHIOCARBONATE
Ferrocenyltrithiocarbonates (I) are readily obtained by treating alpha-ferrocenylcarbinols (II) successively with sodium hydride, carbon disulfide and alkyl halide.Formation of I occurs by intramolecular nucleophilic displacement of oxygen by sulfur with retention of configuration.This is supported by the nature of the other products formed and by the X-ray structure determination of an optically active compound I, which was refined to R = 0.038.The title compound of R configuration was obtained from (R)-ferrocenylmethylmethanol.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application of 31886-57-4. In my other articles, you can also check out more blogs about 31886-57-4
Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis