Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3411-48-1, is researched, SMILESS is C1=CC2=C(C=C1)C(=CC=C2)P(C1=CC=CC2=C1C=CC=C2)C1=CC=CC2=C1C=CC=C2, Molecular C30H21PJournal, Article, Research Support, Non-U.S. Gov’t, Organic Letters called Regioselective trans-Carboboration of Propargyl Alcohols, Author is Jin, Hongming; Fuerstner, Alois, the main research direction is regioselective trans carboboration propargyl alc; crystal mol structure dioxaborolanyl butenol hexenol boracycle.Name: Tri(naphthalen-1-yl)phosphine.
Proper choice of the base allowed trans-diboration of propargyl alcs. with B2(pin)2 to evolve into an exquisitely regioselective procedure for net trans-carboboration. The method is modular as to the newly introduced carbon substituent (aryl, Me, allyl, benzyl, alkynyl), which is invariably placed distal to the -OH group.
When you point to this article, it is believed that you are also very interested in this compound(3411-48-1)Name: Tri(naphthalen-1-yl)phosphine and due to space limitations, I can only present the most important information.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis