Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 14389-12-9, is researched, SMILESS is C1(C2=NN=NN2)=CC=NC=C1, Molecular C6H5N5Journal, CrystEngComm called New (3,4)-connected intrinsically chiral topology observed in a homochiral coordination polymer from achiral precursors, Author is Wang, Fei; Zhang, Jian; Chen, Shu-Mei; Xie, Yi-Ming; Wu, Xiao-Yuan; Chen, Shan-Ci; Yu, Rong-Min; Lu, Can-Zhong, the main research direction is copper pyridyltetrazole cyanide bridge coordination polymer solvothermal preparation; crystal structure luminescence copper pyridyltetrazole cyanide bridge coordination polymer; NLO homochirality copper pyridyltetrazole cyanide bridge coordination polymer.SDS of cas: 14389-12-9.
An unpredicted (3,4)-connected topol. with intrinsic chirality present in a homochiral coordination polymer [Cu2(L)CN]n (1; L = 5-(4-pyridyl)tetrazole) was first shown here, which reveals a new possibility for the construction of lowly-connected chiral framework materials with potential applications.
This literature about this compound(14389-12-9)SDS of cas: 14389-12-9has given us a lot of inspiration, and I hope that the research on this compound(5-(4-Pyridyl)-1H-tetrazole) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis