One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, Quality Control of 2,4-Dimethylpyridine, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 108-47-4, Name is 2,4-Dimethylpyridine, molecular formula is C7H9N
Towards an understanding of the oxidative degradation pathways of AMP for post-combustion CO2 capture
Aqueous 2-amino-2-methyl-1-propanol (AMP) solution and the blends of AMP with other amines appear to be commercially attractive solvents for post-combustion CO2 capture by chemical absorption. To get an understanding of the chemistry of AMP oxidation, oxidative degradation of AMP was investigated in a closed-batch autoclave reactor at 80C and in an open-batch photochemical reactor in the presence of UV radiation at 55C. The degradation products were identified or quantified by ion chromatography (IC) and gas chromatography-mass spectrometry (GC-MS). The effect of temperature on final degradation product distribution was discussed based on the results of thermally accelerated AMP oxidation experiments. The degradation products of AMP oxidation in the presence of UV radiation were compared with that identified in the thermally accelerated AMP oxidation. A summarized scheme for AMP oxidation is proposed to account for the formation of all of the identified products.
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Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis