Electric Literature of 108-47-4, In homogeneous catalysis, catalysts are in the same phase as the reactants. Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 108-47-4, Name is 2,4-Dimethylpyridine, molecular formula is C7H9N. In a Article，once mentioned of 108-47-4
Density functional study of alkylpyridine-iodine interaction and its implications in the open-circuit photovoltage of dye-sensitized solar cell
A density functional theory (DFT) method was used to study the monomer and intermolecular charge-transfer complexes of 22 different alkylpyridines with diiodine. DFT calculations revealed that the sigma* orbital of iodine interacts with the nitrogen lone pair in pyridines. The open-circuit photovoltage (Voc) values of a bis(tetrabutylammonium)cis- bis(thiocyanato)bis(2,2?-bipyridine-4-carboxylic acid, 4?-carboxylate)ruthenium(II) (N719) dye-sensitized nanocrystalline TiO2 solar cell with an I-/I3- redox electrolyte in acetonitrile using alkylpyridines additive were compared to computational calculations on the interaction between pyridines and I 2 by a DFT method. The optimized geometries, frequency analyses, Mulliken population analyses, and interaction energies suggest that the V oc value of the solar cell is higher, the more alkylpyridine complexes with I2.
Because enzymes can increase reaction rates by enormous factors and tend to be very specific, they are the focus of active research. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 108-47-4
Reference：
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis