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Transfer hydrogenation catalysis of ketones and imines
The transfer hydrogenation of ketones and imines using RuII, RhIII and IrIII complexes with beta-amino alkoxide and beta-amino sulphonimide ligands has been used for the last 20 years as a practical and powerful tool for the synthesis of alcohols and amines. When compared to Noyori hydrogenation under H2 pressure, e.g. catalysts of the type [(diphosphine)RuCl2(diamine)], which uses basic co-catalysts and requires access to pressure equipment, transfer hydrogenation is much more versatile and often more cost effective. The aim of this review is to highlight the large number of available process conditions that promise to give cost-efficient reductions of complex substrates, demonstrating the incredible versatility and effectiveness of this technology.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Quality Control of (1S,2R)-1-Amino-2,3-dihydro-1H-inden-2-ol, you can also check out more blogs about126456-43-7
Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis