108-47-4, Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 108-47-4, Name is 2,4-Dimethylpyridine
POTENTIOMETRIC STUDIES ON COMPLEXES OF SILVER(I) IN SOLUTIONS. PART V. RELATIONSHIP BETWEEN STABILITY CONSTANTS OF Ag(I) COMPLEXES OF PYRIDINE DERIVATIVES AND HAMMET’S ? COEFFICIENTS
By means of the potentiometric method, the processes of formation of Ag(I) complexes of 3-acetyl-, 3-hydroxymethyl-, 2-ethyl-, 2,4-dimethyl-, 2,4,6-trimethyl-, 2-amino-5-methyl-, and 2-amino-4-methylpyridines have been examined in aqueous solutions (I = 0.5 (KNO3), t = 25 deg C).Correlation has been found between pKa and stability coefficient Sf and substituent constants ? for 19 Ag(I) compounds with 3- and 4-substituted pyridine derivatives.Positive value of the slope of Sf = f(?) straight line dependence evidences that the contribution of ?M -> L bond in the metal-ligand co-ordination bond is considerable.
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Reference£º
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis