Flexible application of in synthetic route 1663-45-2

Although many compounds look similar to this compound(1663-45-2)Computed Properties of C26H24P2, numerous studies have shown that this compound(SMILES:P(CCP(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called The geometric and electronic structures of a Ag13Cu10(SAdm)12X3 nanocluster, published in 2020, which mentions a compound: 1663-45-2, Name is 1,2-Bis(diphenylphosphino)ethane, Molecular C26H24P2, Computed Properties of C26H24P2.

Herein, authors report the synthesis and total structure of a Cu-rich alloy nanocluster protected by twelve adamantanethiolate ligands, i.e., [Ag13Cu10(SAdm)12]X3 (-SAdm = SC10H15, X = counterion), which was confirmed by single-crystal x-ray structure determination and electrospray ionization mass spectrometry (ESI-MS). X-ray crystallog. anal. indicated that [Ag13Cu10(SAdm)12]X3 consisted of an icosahedral Ag13 core, covered by a cage-like shell of Cu10(SAdm)12. Furthermore, d. functional theory (DFT) and time-dependent DFT (TD-DFT) calculations on the geometric and electronic structures and KS orbitals and UV-vis spectroscopy were performed on the model [Ag13Cu10(SMe)12]3+ and its monometallic analog [Ag23(SMe)12]3+. This work will deepen the understanding of core-shell Ag-Cu alloy nanoclusters.

Although many compounds look similar to this compound(1663-45-2)Computed Properties of C26H24P2, numerous studies have shown that this compound(SMILES:P(CCP(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis