A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Product Details of 4355-11-7, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 4355-11-7, Name is 1,1-Cyclohexanediaceticacid, molecular formula is C10H16O4. In an article, author is Musina, E. I.,once mentioned of 4355-11-7.
Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes
Novel 1,9-diaza-3,7,11,15-tetraphosphacyclohexadecanes with alkyl, arylalkyl, or heteroarylalkyl substituents at the endocyclic nitrogen atoms were synthesized by condensation of 1,3-bis(phenylphosphino)propane, formaldehyde, and primary amines. The reactions are stereoselective and result in the isomer with the RSSR configuration of the phosphorus atoms as the major product. The 16-membered tetrakis(phosphine) ligands form stable neutral tetranuclear complexes with gold(I). In these complexes, the 16-membered cyclic ligands retain their free-state conformations and the configuration of the chiral phosphorus atoms.
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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis