Related Products of 2344-80-1, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, 2344-80-1, Name is (Chloromethyl)trimethylsilane, SMILES is C[Si](C)(CCl)C, belongs to chiral-nitrogen-ligands compound. In a article, author is Davies, Stephen G., introduce new discover of the category.
Solid state conformations of alpha,beta-unsaturated hydroxamates derived from the ‘chiral Weinreb amide’ auxiliary (S)-N-1-(1 ‘-naphthyl)-ethyl-O-tert-butylhydroxylamine
alpha,beta-Unsaturated hydroxamates derived from the ‘chiral Weinreb amide’ auxiliary (S)-N-1-(1′-naphthyl) ethyl-O-tert-butylhydroxylamine consistently adopt a defined conformation and undergo highly diastereoselective conjugate addition reactions with lithium amide reagents. The configuration of the N-1-(1′-naphthyl)ethyl group dictates the position of the O-tert-butyl group and also the configuration adopted by the pyramidal nitrogen atom via a ‘chiral relay’ effect. Conjugate addition of lithium amide reagents to these substrates proceeds on the face opposite to both the O-tert-butyl group and nitrogen lone-pair with high levels of diastereoselectivity. (C) 2017 Elsevier Ltd. All rights reserved.
Related Products of 2344-80-1, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 2344-80-1.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis