Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 136030-00-7, Name is (1R,2S)-1-Amino-2,3-dihydro-1H-inden-2-ol. In a document, author is Sirvent, Ana, introducing its new discovery. Formula: C9H11NO.
Diastereoselective Homoallylation and Bis-homoallylation of N-tert-butanesulfinyl Imines with Organomagnesium Compounds
The addition of but-3-enylmagnesium bromide and pent-4-enylmagnesium bromide to N-tert-butanesulfinyl aldimines in toluene as solvent proceeds with high diastereoselectivity to yield the corresponding products of homoallylation and bis-homoallylation, respectively. The reactions are diastereoselective, and the configuration of the sulfur atom of the sulfinyl group determined the stereochemical outcome. The reaction products are aminoalkene derivatives of potential synthetic interest as precursors of nitrogen containing heterocycles.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 136030-00-7 help many people in the next few years. Formula: C9H11NO.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis