Product Details of 14389-12-9. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Hydrothermal Preparation of Novel Cd(II) Coordination Polymers Employing 5-(4-Pyridyl)tetrazolate as a Bridging Ligand. Author is Xue, Xiang; Wang, Xi-Sen; Wang, Li-Zhong; Xiong, Ren-Gen; Abrahams, Brendan F.; You, Xiao-Zeng; Xue, Zi-Ling; Che, Chi-Ming.
The reaction of 4-cyanopyridine with NaN3 in the presence of H2O and a Lewis acid (CdCl2) affords a novel 3-dimensional pillared-layered fluorescent and phosphorescent coordination polymer Cd3(OH)2Cl2(4-PTZ)2 (4-PTZ = 5-(4-pyridyl)tetrazolate) (1) while the direct reaction of CdCl2 with H-PTZ gives the simpler species Cd(4-PTZ)2(H2O)2. The solid-state structure and nature of 1 provide an indication of the type of materials that may be formed as intermediates in the Sharpless-Demko reaction for the generation of 5-substituted 1H-tetrazoles.
The article 《Hydrothermal Preparation of Novel Cd(II) Coordination Polymers Employing 5-(4-Pyridyl)tetrazolate as a Bridging Ligand》 also mentions many details about this compound(14389-12-9)Product Details of 14389-12-9, you can pay attention to it, because details determine success or failure
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis