The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, and their interactions with reaction intermediates and transition states. In an article, 108-47-4, name is 2,4-Dimethylpyridine, introducing its new discovery. category: chiral-nitrogen-ligands
Aqueous 2-amino-2-methyl-1-propanol (AMP) solution and the blends of AMP with other amines appear to be commercially attractive solvents for post-combustion CO2 capture by chemical absorption. To get an understanding of the chemistry of AMP oxidation, oxidative degradation of AMP was investigated in a closed-batch autoclave reactor at 80C and in an open-batch photochemical reactor in the presence of UV radiation at 55C. The degradation products were identified or quantified by ion chromatography (IC) and gas chromatography-mass spectrometry (GC-MS). The effect of temperature on final degradation product distribution was discussed based on the results of thermally accelerated AMP oxidation experiments. The degradation products of AMP oxidation in the presence of UV radiation were compared with that identified in the thermally accelerated AMP oxidation. A summarized scheme for AMP oxidation is proposed to account for the formation of all of the identified products.
The design and synthesis of related molecules that are more effective, more selective, and less toxic than aspirin are important objectives of biomedical research.category: chiral-nitrogen-ligands, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 108-47-4, in my other articles.
Reference：
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis