Chiral nitrogen ligands

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Basicity of Very Weak Bases in 1,2-Dichloroethane, published in 2016, which mentions a compound: 3411-48-1, Name is Tri(naphthalen-1-yl)phosphine, Molecular C30H21P, Category: chiral-nitrogen-ligands.

The basicity scale of very weak bases has been set up in 1,2-dichloroethane to give, for the first time, reliable quant. insights into the basic properties of weak bases in a low-polarity solvent. The scale contains 30 compounds, including anilines; phosphanes, and carbonyl bases, such as esters and amides, linked by 53 relative basicity measurements. The scale spans more than 12 pKip units, expanding to as low pKip values as possible with our current exptl. methodol.

Different reactions of this compound(Tri(naphthalen-1-yl)phosphine)Category: chiral-nitrogen-ligands require different conditions, so the reaction conditions are very important.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 2-Aminoquinazolin-4(3H)-one, is researched, Molecular C8H7N3O, CAS is 20198-19-0, about Synthesis of potential fungicides in the quinazoline series, the main research direction is quinazoline derivative preparation fungicide; pyrimidoquinazoline preparation fungicide; polymethylenequinazoline fungicide; formylation polymethylenequinazoline; bromination polymethylenequinazoline; chlorosulfonation polymethylenequinazoline.Reference of 2-Aminoquinazolin-4(3H)-one.

Acylaminoquinazolines I (R = MeO, Me, Me2CHCH2, Ph, benzyl, PhCH:CH, p-O2NC6H4, p-MeOC6H4, p-tolyl, 3,5-xylyl) were obtained in 20-69% yield by acylation of the resp. amine. Pyrimidoquinazolines II (R1-3 = H; R1-2 = H, R3 = Me; R1 = Me, R2-3 = H; R1-2 = Me, Ph, R3 = H) were obtained in 61-90% yield by cycloaddition of R1CR2:CR3CO2H with the amine. Polymethylenedihydroquinazolones III (n = 1, 2, 3) were brominated, chlorosulfonated, nitrated and formylated to give 6.1-100% expected products. Aminomethylene derivative IV (X = e.g., NO2; n = 1, 2, 3; NR4R5 = piperidino, morpholino; R4 = R5 = H, Me; R4 = H, R5 = OH, Bu, Me2CHCH2, CMe3) were also prepared Condensation of III (n = 1) with 26 aldehydes and ketones gave V e.g., R6 = Ph, R7 = H). The prepared compounds had low fungicidal activity (no data).

Different reactions of this compound(2-Aminoquinazolin-4(3H)-one)Reference of 2-Aminoquinazolin-4(3H)-one require different conditions, so the reaction conditions are very important.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

COA of Formula: C26H24P2. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 1,2-Bis(diphenylphosphino)ethane, is researched, Molecular C26H24P2, CAS is 1663-45-2, about Understanding the acrylates formation from CO2 and ethylene over Ni- and Pd-based catalysts: A DFT study on the effects of solvents, methyl halides, and ligands. Author is Zhu, Youcai; Guo, Xing; Ding, Xinxin; Sun, Li; Zhang, Mingguo; Liu, Zhen.

In this work, two methylation reaction pathways were investigated to explore the role of solvent and I- on the formation of Me acrylate from coupling of CO2 and ethylene catalyzed by nickel and palladium catalysts in the presence of MeI. The stabilization of non-productive intermediates is inhibited in the gas phase as well as in low-polar solvents, which explains the requirement of high excess of MeI to obtain high yields of Me acrylate. The energy barrier for M-O bond cleavage as well as the stability of the overall reaction intermediates is consistent with the corresponding halogen electron-donating ability. The different catalytic behaviors of various bidentate ligands on Ni- and Pd-based catalysts were systematically investigated, mainly including dmpe(1,2-bis(dimethylphosphino)ethane), tmeda(tetramethylethylenediamine), dppe(1,2-bis(diphenylphosphino)ethane), dcpe(1,2-bis(dicyclohexylphosphino)ethane) and dtbpe(1,2-bis(di-tert-butylphosphino)ethane). The energy barrier of M-O bond cleavage increases with the enhancement of ligand steric hindrance in the O1 (ester sp3 O atom) attack mechanism, while the corresponding O2 (carboxylic sp2 O atom) attack mechanism shows an opposite trend. The energy barrier of β-H elimination in both catalytic systems is strongly related to the electron-donating ability of the diphosphine ligand substituents. The dcpp(1,3-bis(dicyclohexylphosphino)propane) ligand shows relatively good performance for β-H elimination among all the investigated ligands in Pd-mediated system. In general, diphosphine ligands are superior to diamine ligands in Pd-mediated system in terms of efficiency.

Different reactions of this compound(1,2-Bis(diphenylphosphino)ethane)COA of Formula: C26H24P2 require different conditions, so the reaction conditions are very important.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 14389-12-9, is researched, SMILESS is C1(C2=NN=NN2)=CC=NC=C1, Molecular C6H5N5Journal, Article, Acta Crystallographica, Section E: Structure Reports Online called Triaquadichlorido[5-(4-pyridinio)tetrazolato-κN2]cobalt(II) monohydrate, Author is Wang, Bo, the main research direction is crystal structure cobalt pyridinio tetrazolato chloro aqua complex monohydrate; mol structure cobalt pyridiniotetrazolato chloro aqua complex hydrate; hydrogen bond cobalt pyridiniotetrazolato chloro aqua complex monohydrate; pi stacking cobalt pyridiniotetrazolato chloro aqua complex monohydrate; tetrazolato pyridinio cobalt chloro aqua monohydrate crystal mol structure.SDS of cas: 14389-12-9.

Triaquadichloro[5-(4-pyridinio)tetrazolato-κN2]cobalt monohydrate, [CoCl2(C6H5N5)(H2O)3]·H2O, was synthesized by hydrothermal reaction of CoCl2 with 4-(2H-tetrazol-5-yl)pyridine. The CoII cation is coordinated by 2 Cl- ions, 1 N atom from the 5-(4-pyridinio)tetrazolate zwitterion and 3 O atoms from 3 H2O mols. in a distorted octahedral geometry. In the crystal, mols. are linked into a 3-dimensional network by N-H···Cl H bonds and O-H···O/N/Cl H bonds involving both coordinated and uncoordinated H2O mols. Strong π-π stacking is present between parallel pyridinium and tetrazolate rings [centroid-centroid distances = 3.411(2) and 3.436(2) Å]. Crystallog. data are given.

The article 《Triaquadichlorido[5-(4-pyridinio)tetrazolato-κN2]cobalt(II) monohydrate》 also mentions many details about this compound(14389-12-9)SDS of cas: 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 1,5-Dibromopentane, is researched, Molecular C5H10Br2, CAS is 111-24-0, about How does methylviologen cation radical supply two electrons to the formate dehydrogenase in the catalytic reduction process of CO2 to formate, the main research direction is methylviologen radical electron supply formate dehydrogenase carbon dioxide reduction; carbon dioxide catalytic reduction formate mechanism density functional theory.Recommanded Product: 111-24-0.

Formate dehydrogenase from Candida boidinii (CbFDH) is a com. available enzyme and can be easily handled as a catalyst for the CO2 reduction to formate in the presence of NADH, single-electron reduced methylviologen (MV+. ) and so on. It was found that the formate oxidation to CO2 with CbFDH was suppressed using the oxidized MV as a co-enzyme and the single-electron reduced MV (MV+. ) was effective for the catalytic activity of CbFDH for the CO2 reduction to formate compared with that using the natural co-enzyme of NADH. The CO2 reduction to formate catalyzed by CbFDH requires two mols. of the MV+. . In order to clarify the two-electron reduction process using MV+. in the CO2 reduction to formate catalyzed with CbFDH, we attempted enzyme reaction kinetics, electrochem. and quantum chem. analyses. Kinetic parameters obtained from the enzymic kinetic anal. metric revealed an index of affinity of MV+. for CbFDH in the CO2 reduction to formate. From the results of the electrochem. anal., it was predicted that only one mol. of MV+. was bound to CbFDH, and the MV bound to CbFDH was to be necessarily re-reduced by the electron source outside of CbFDH to supply the second electron in the CO2 reduction to formate.

The article 《How does methylviologen cation radical supply two electrons to the formate dehydrogenase in the catalytic reduction process of CO2 to formate》 also mentions many details about this compound(111-24-0)Recommanded Product: 111-24-0, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 1,2-Bis(diphenylphosphino)ethane(SMILESS: P(CCP(C1=CC=CC=C1)C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4,cas:1663-45-2) is researched.Product Details of 14389-12-9. The article 《Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane》 in relation to this compound, is published in Inorganic Chemistry. Let’s take a look at the latest research on this compound (cas:1663-45-2).

Three novel palladium(II) mixed-ligand complexes of N-(benzothiazol-2-yl)benzamide (HL) and 1,2-bis(diphenylphosphino)ethane (dppe), [Pd(HL)(dppe)]Cl2 (1), [Pd(L)(dppe)]Cl (2), and [Pd(L)2(dppe)] (3), were synthesized and fully characterized using Fourier transform IR, 1H, 13C, and 31P NMR, and molar conductivity measurements. Complex 3 was characterized by single-crystal X-ray diffraction. The ligand HL showed three different coordination modes: a neutral bidentate chelate bound through the endocyclic nitrogen and exocyclic oxygen atoms in 1, a neg. charged L bound as a bidentate chelate through the endocyclic nitrogen and neg. charged exocyclic oxygen atoms in 2, and a monodentate bound through the neg. charged endocyclic nitrogen atom in 3.

The article 《Synthesis and Structural Characterization of Palladium(II) Mixed-Ligand Complexes of N-(Benzothiazol-2-yl)benzamide and 1,2-Bis(diphenylphosphino)ethane》 also mentions many details about this compound(1663-45-2)HPLC of Formula: 1663-45-2, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Product Details of 14389-12-9. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Zinc chloride-catalyzed synthesis of 5-substituted 1H-tetrazoles under solvent free condition. Author is Rostamizadeh, Shahnaz; Ghaieni, Hamid; Aryan, Reza; Amani, Ali.

Zinc chloride is an efficient and safe catalyst in the [3 + 2] cycloaddition reaction of organic nitriles with sodium azide in solventless condition. The corresponding 5-substituted 1H tetrazoles were obtained under mild conditions. This method can overcome disadvantages such as: the use of toxic metals and expensive reagents, drastic reaction conditions, water sensitivity and the presence of dangerous hydrazoic acid.

The article 《Zinc chloride-catalyzed synthesis of 5-substituted 1H-tetrazoles under solvent free condition》 also mentions many details about this compound(14389-12-9)Product Details of 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Category: chiral-nitrogen-ligands. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Expanded perlite: an inexpensive natural efficient heterogeneous catalyst for the green and highly accelerated solvent-free synthesis of 5-substituted-1H-tetrazoles using [bmim]N3 and nitriles. Author is Jahanshahi, Roya; Akhlaghinia, Batool.

A versatile, green and highly accelerated protocol for preparing 5-substituted-1H-tetrazoles was reported. In this method, 5-substituted-1H-tetrazoles were synthesized from nitriles and [bmim]N3, in the presence of the expanded perlite as an inexpensive natural efficient heterogeneous catalyst, under solvent-free condition. A wide variety of aryl nitriles underwent [3+2] cycloaddition to afford the desired tetrazoles in good to excellent yields, rapidly. This method had the advantages of high yields, short reaction times, simple methodol. and easy work-up. The catalyst was recovered by simple filtration and reused delivering good yields.

The article 《Expanded perlite: an inexpensive natural efficient heterogeneous catalyst for the green and highly accelerated solvent-free synthesis of 5-substituted-1H-tetrazoles using [bmim]N3 and nitriles》 also mentions many details about this compound(14389-12-9)Category: chiral-nitrogen-ligands, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Wang, Fei; Zhang, Jian; Yu, Rongmin; Chen, Shu-Mei; Wu, Xiao-Yuan; Chen, Shan-Ci; Xie, Yi-Ming; Zhou, Wei-Wei; Lu, Can-Zhong published the article 《Topological derivation from centrosymmetry to noncentrosymmetry in a three-dimensional polar framework material》. Keywords: copper bromo pyridyltetrazole polymeric complex preparation SHG.They researched the compound: 5-(4-Pyridyl)-1H-tetrazole( cas:14389-12-9 ).SDS of cas: 14389-12-9. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:14389-12-9) here.

Strong second harmonic generation (SHG) response was presented by a three-dimensional polar framework material [Cu2(L)Br]n (1; HL = 5-(4-pyridyl)tetrazole), which was obtained by reacting CuBr with HL under solvothermal conditions and displayed an noncentrosym. (3,4)-connected topol. derived from the centrosym. CdSO4 net.

The article 《Topological derivation from centrosymmetry to noncentrosymmetry in a three-dimensional polar framework material》 also mentions many details about this compound(14389-12-9)SDS of cas: 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis

Product Details of 14389-12-9. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Hydrothermal Preparation of Novel Cd(II) Coordination Polymers Employing 5-(4-Pyridyl)tetrazolate as a Bridging Ligand. Author is Xue, Xiang; Wang, Xi-Sen; Wang, Li-Zhong; Xiong, Ren-Gen; Abrahams, Brendan F.; You, Xiao-Zeng; Xue, Zi-Ling; Che, Chi-Ming.

The reaction of 4-cyanopyridine with NaN3 in the presence of H2O and a Lewis acid (CdCl2) affords a novel 3-dimensional pillared-layered fluorescent and phosphorescent coordination polymer Cd3(OH)2Cl2(4-PTZ)2 (4-PTZ = 5-(4-pyridyl)tetrazolate) (1) while the direct reaction of CdCl2 with H-PTZ gives the simpler species Cd(4-PTZ)2(H2O)2. The solid-state structure and nature of 1 provide an indication of the type of materials that may be formed as intermediates in the Sharpless-Demko reaction for the generation of 5-substituted 1H-tetrazoles.

The article 《Hydrothermal Preparation of Novel Cd(II) Coordination Polymers Employing 5-(4-Pyridyl)tetrazolate as a Bridging Ligand》 also mentions many details about this compound(14389-12-9)Product Details of 14389-12-9, you can pay attention to it, because details determine success or failure

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis