A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 26544-38-7, Name is 3-(Dodec-2-en-1-yl)dihydrofuran-2,5-dione, molecular formula is C16H26O3. In an article, author is Ametovski, Jhi,once mentioned of 26544-38-7, Name: 3-(Dodec-2-en-1-yl)dihydrofuran-2,5-dione.
Phosphine catalysed (5+1) annulation of ynone/cinnamates with primary amines
The (5 + 1) annulation of ynone/cinnamates and related substrates with protected primary amines gives rise to isoquinolones, pyrrolidinones and pyrrolopiperazines in good to excellent yields under phosphine catalysis. The reaction is viable with chiral phosphines, although the selectivity is poor.
Interested yet? Keep reading other articles of 26544-38-7, you can contact me at any time and look forward to more communication. Name: 3-(Dodec-2-en-1-yl)dihydrofuran-2,5-dione.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis