The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 26544-38-7, Name is 3-(Dodec-2-en-1-yl)dihydrofuran-2,5-dione, SMILES is O=C(O1)C(C/C=C/CCCCCCCCC)CC1=O, in an article , author is Buss, Oliver, once mentioned of 26544-38-7, Formula: C16H26O3.
Enantiomer discrimination in beta-phenylalanine degradation by a newly isolated Paraburkholderia strain BS115 and type strain PsJN
Despite their key role in numerous natural compounds, beta-amino acids have rarely been studied as substrates for microbial degradation. Fermentation of the newly isolated Paraburkholderia strain BS115 and the type strain P. phytofirmans PsJN with beta-phenylalanine (beta-PA) as sole nitrogen source revealed (S)-selective transamination of beta-PA to the corresponding beta-keto acid by both strains, accompanied by substantial formation of acetophenone (AP) from spontaneous decarboxylation of the emerging beta-keto acid. While the PsJN culture became stationary after entire (S)-beta-PA consumption, BS115 showed further growth at a considerably slower rate, consuming (R)-beta-PA without generation of AP which points to a different degradation mechanism for this enantiomer. This is the first report on degradation of both enantiomers of any beta-amino acid by one single bacterial strain.
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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis