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Electric Literature of 108-47-4, Chemistry involves the study of all things chemical – chemical processes, chemical compositions and chemical manipulation – in order to better understand the way in which materials are structured, how they change and how they react in certain situations. 108-47-4, Name is 2,4-Dimethylpyridine, molecular formula is C7H9N. In a article，once mentioned of 108-47-4
The kinetics of the forward and reverse steps of the process Cl>(1+) + am –>/<-- (am)>(2+) + Cl(1-) has been studied in methanol at 25 deg C.Both forward and reverse reactions obey the usual two-term rate law observed in square-planar substitution.The second-order rate constants for the forward reactions, k2f, show only a slight dependence upon the basicity of the entering am, and steric hindrance markedly decreases the reactivity.The second-order rate constants for the reverse reactions, k2r, are very sensitive to the nature of the leaving group and plots of log k2r against the pKa of the conjugate acids of unhindered pyridines with different ? systems are linear with a slope of -0.45.A comparison among the different pyridines and sp3 nitrogen donor bases indicates an appreciable ? contribution to the stability of the Pt-N(sp2) bond.The equilibrium constants for the reactions have been determined in a number of cases from the ratio of the rate constants and a plot of log K against the pKa is linear with a slope of 0.66.The results are compared with data from the literature.
One of the oldest and most widely used commercial enzyme inhibitors is aspirin, which selectively inhibits one of the enzymes involved in the synthesis of molecules that trigger inflammation. Electric Literature of 108-47-4, In my other articles, you can also check out more blogs about Electric Literature of 108-47-4
Reference：
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis