Synthetic Route of 108-47-4, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 108-47-4, 2,4-Dimethylpyridine, introducing its new discovery.
Design and synthesis of tridentate facially chelating ligands of the [2.n.1]-(2,6)-Pyridinophane family
Syntheses are reported for tripyridine macrocycles 2 and 3 and some of their alkyl derivatives. The macrocycles are designed to stabilize to various extents coordinated d8 metal precursors and d6 alkane oxidative addition products (ptIV), therefore allowing favorable kinetics and thermodynamics of (e.g., PtII) the cleavage of substrate H-C(sp3) bonds. Both the Chichibabin protocol and oxidative coupling of carbanions by copper(I) iodide were used for the macrocyclization step. Crystal structures of singly and doubly protonated 2 establish atom connectivity in the macrocycle, and reveal structural features which are obscured in solution NMR by rapid proton migration.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Synthetic Route of 108-47-4. In my other articles, you can also check out more blogs about 108-47-4
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Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis