Electric Literature of 108-47-4, Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels.108-47-4, Name is 2,4-Dimethylpyridine, molecular formula is C7H9N. In a article£¬once mentioned of 108-47-4
Solvent Effect on CuCl2-Pyridine Derivative Complexes: UV-VIS ans E.S.R. Study of the CuCl2-2,4-Dimethylpyridine-Solvent Systems
The electronic (400 – 800 nm; 298.2 K) and E.S.R. spectra (298 K; 77K) have been measured for CuCl2-2,4-dimethylpyridine(2,4-Me2py)-solvent systems (solvents: aliphatic and aromatic hydrocarbons, carbon tetrachloride, chloroform, 1,1,2,2-tetrachloroethane).In all the media CuCl2 forms electrically neutral strongly distorted six-coordinated complexes, the extent of tetragonality being greater than for analogous complexes with non-alpha-substituted pyridines.In contrast to aliphatic and aromatic hydrocarbons protic solvents and, unexpectedly, aprotic carbon tetrachloride solvate the CuCl2-Me2py complex comparatively strongly, most probably through interactions with the chlorine ligand.The results for 2,4-Me2py were compared with those for pyridine, 4-ethylpyridine and isoquinoline and discussed in terms of steric effects on solvation.In particular, alpha-substitution seems to hinder the solvation of the complex by the amine. – Keywords: Solvent effect; Copper(II) chloride complexes; Pyridine derivative complexes
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Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis