Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 5-(4-Pyridyl)-1H-tetrazole, is researched, Molecular C6H5N5, CAS is 14389-12-9, about Understanding the formation of metal-oxide based inorganic solids: Assessing the influence of tetrazole molecule.Computed Properties of C6H5N5.
The hydrothermal reaction of Cu(II) salt, ammonium heptamolybdate and 4-ptz (5-(4-pyridyl)tetrazole) at different synthetic conditions yields two compounds [Cu(4-Hptz)(Mo2O7)] (1) and [Cu(4-Hptz)2(H2O)3]2[Mo8O26] (2). Both the compounds 1 and 2 were characterized by routine elemental analyses, IR-, thermogravimetric studies and unambiguously characterized by single crystal x-ray crystallog. Compound 1 exhibits a 3-dimensional bimetallic oxide framework, constructed from the tetrazoles and {CuMo2O7} oxide phase. The coordination ability of N atoms in the tetrazole ring makes the ring acting as a template in the formation of {Cu4Mo6O10} rings, made up of [Mo2O7]2- anions and Cu(II) octahedra; the stacking of these {Cu4Mo6O10} rings along crystallog. c axis gave a 3-dimensional bimetallic oxide framework. Compound 2 consists of infinite octamolybdate chains and Cu-tetrazolate complex cation. The formation of oxide phase under hydrothermal conditions is discussed, giving importance of the role of geometry of the tetrazole ring.
There is still a lot of research devoted to this compound(SMILES：C1(C2=NN=NN2)=CC=NC=C1)Computed Properties of C6H5N5, and with the development of science, more effects of this compound(14389-12-9) can be discovered.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis