Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3411-48-1, is researched, SMILESS is C1=CC2=C(C=C1)C(=CC=C2)P(C1=CC=CC2=C1C=CC=C2)C1=CC=CC2=C1C=CC=C2, Molecular C30H21PJournal, Article, Acta Crystallographica, Section E: Structure Reports Online called (Acetylacetonato-κ2O,O’)carbonyl[tris(naphthalen-1-yl)phosphane-κP]rhodium(I) acetone hemisolvate, Author is Ogutu, Hezron; Meijboom, Reinout, the main research direction is mol structure rhodium acetylacetonato carbonyl naphthalenylphosphane complex acetone solvate; crystal structure rhodium acetylacetonato carbonyl naphthalenylphosphane complex acetone solvate.Application In Synthesis of Tri(naphthalen-1-yl)phosphine.
The title compound, [Rh(C5H7O2)(C30H21P)(CO)]·0.5C3H6O, has two different complex mols. in the asym. unit, with the RhI atoms in slightly distorted square-planar coordination environments. The mols. are packed as two monomeric mols. with one acetone solvent mol. sitting at the center. Crystallog. data and at. coordinates are given.
Although many compounds look similar to this compound(3411-48-1)Application In Synthesis of Tri(naphthalen-1-yl)phosphine, numerous studies have shown that this compound(SMILES:C1=CC2=C(C=C1)C(=CC=C2)P(C1=CC=CC2=C1C=CC=C2)C1=CC=CC2=C1C=CC=C2), has unique advantages. If you want to know more about similar compounds, you can read my other articles.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis