The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 1,5-Dibromopentane, is researched, Molecular C5H10Br2, CAS is 111-24-0, about How does methylviologen cation radical supply two electrons to the formate dehydrogenase in the catalytic reduction process of CO2 to formate, the main research direction is methylviologen radical electron supply formate dehydrogenase carbon dioxide reduction; carbon dioxide catalytic reduction formate mechanism density functional theory.Recommanded Product: 111-24-0.
Formate dehydrogenase from Candida boidinii (CbFDH) is a com. available enzyme and can be easily handled as a catalyst for the CO2 reduction to formate in the presence of NADH, single-electron reduced methylviologen (MV+. ) and so on. It was found that the formate oxidation to CO2 with CbFDH was suppressed using the oxidized MV as a co-enzyme and the single-electron reduced MV (MV+. ) was effective for the catalytic activity of CbFDH for the CO2 reduction to formate compared with that using the natural co-enzyme of NADH. The CO2 reduction to formate catalyzed by CbFDH requires two mols. of the MV+. . In order to clarify the two-electron reduction process using MV+. in the CO2 reduction to formate catalyzed with CbFDH, we attempted enzyme reaction kinetics, electrochem. and quantum chem. analyses. Kinetic parameters obtained from the enzymic kinetic anal. metric revealed an index of affinity of MV+. for CbFDH in the CO2 reduction to formate. From the results of the electrochem. anal., it was predicted that only one mol. of MV+. was bound to CbFDH, and the MV bound to CbFDH was to be necessarily re-reduced by the electron source outside of CbFDH to supply the second electron in the CO2 reduction to formate.
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Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis