The Absolute Best Science Experiment for C5H10O

Interested yet? Read on for other articles about 96-47-9, you can contact me at any time and look forward to more communication. SDS of cas: 96-47-9.

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 96-47-9, Name is 2-Methyltetrahydrofuran, SMILES is CC1OCCC1, in an article , author is Ma, Dengke, once mentioned of 96-47-9, SDS of cas: 96-47-9.

Organocatalytic Enantioselective Functionalization of Unactivated Indole C(sp(3))-H Bonds

Described here is a direct catalytic asymmetric functionalization of unactivated alkyl indoles using organocatalysis. In the presence of an effective chiral urea catalyst and a phosphoric acid additive, the intermolecular C-C bond formation between alkyl indoles and trifluoropyruvates proceeded with high efficiency and enantiocontrol. Unlike previous asymmetric C(sp(3)-H) functionalizations of alpha-azaarenes, this process does not require the use of either a strong base or an electron-deficient substrate. The excellent enantiocontrol is particularly noteworthy in view of the severe background reaction as well as the complete inability of other types of catalysts evaluated. Control experiments, kinetic studies, and DFT calculations provided important insights into the mechanism.

Interested yet? Read on for other articles about 96-47-9, you can contact me at any time and look forward to more communication. SDS of cas: 96-47-9.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis