Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 2344-80-1, Name is (Chloromethyl)trimethylsilane, molecular formula is C4H11ClSi, belongs to chiral-nitrogen-ligands compound. In a document, author is Ranzenigo, Anna, introduce the new discover, Recommanded Product: (Chloromethyl)trimethylsilane.
Regioselective Deuteration of a 3,4-Dialkoxypyrroline N-Oxide and Synthesis of 8a-d-Indolizidines
A simple and efficient method for C-2 deuterium labeling of 3,4-di-tert-butoxypyrroline N-oxide, a useful chiral building block in azaheterocycles syntheses, is presented. Selective and quantitative deuterium incorporation (> 99 %) was achieved by base-catalyzed H/D exchange in D2O under mild reaction conditions. A mechanistic pathway based on kinetic and computational data was proposed. The labeled nitrone was used in the synthesis of C-8a deuterated (1R,2R,8aR)-lentiginosine.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 2344-80-1. Recommanded Product: (Chloromethyl)trimethylsilane.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis