2344-80-1, Name is (Chloromethyl)trimethylsilane, molecular formula is C4H11ClSi, belongs to chiral-nitrogen-ligands compound, is a common compound. In a patnet, author is Nakano, Momoe, once mentioned the new application about 2344-80-1, Formula: C4H11ClSi.
Accelerated Organic Photoreactions in Flow Microreactors under Gas-Liquid Slug Flow Conditions Using N-2 Gas as an Unreactive Substance
In this work, the [2+2] photocycloaddition of carbonyl compounds with olefins, the Paterno-Biichi-type photoreaction, was performed in a flow microreactor under slug flow (two-phase flow) conditions which are constructed by alternatively introducing nitrogen gas as an unreactive substance into the organic reaction phase. The use of N-2 gas-liquid slug flow conditions permitted the organic photoreactions to proceed more efficiently compared to one-phase flow conditions. A detailed investigation of the influence of the flow mode, the viscosity of the solvents, and the segment length (length of each phase) on the efficiency of the photoreaction was conducted. Based on the results, we concluded that these three factors contribute to the improvement in photoreaction efficiency under slug flow conditions using N-2 gas as an unreactive substance. Further- more, the use of N-2 gas as an unreactive substance was found to be applicable to other Paterno-Biichi-type photoreactions.
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Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis