Gerritsen, L. A.; Klut, W.; Vreugdenhil, M. H.; Scholten, J. J. F. published an article about the compound: Tri(naphthalen-1-yl)phosphine( cas:3411-48-1,SMILESS:C1=CC2=C(C=C1)C(=CC=C2)P(C1=CC=CC2=C1C=CC=C2)C1=CC=CC2=C1C=CC=C2 ).Recommanded Product: 3411-48-1. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:3411-48-1) through the article.
The heterogeneous catalytic hydroformylation of propylene is carried out at 90-199° and 1.57 MPa total pressure over a supported liquid phase Rh catalyst. Tri-p-tolylphosphine, tris(2-cyanoethyl)phosphine and S-(+)-(2-phenylbutyl)diphenylphosphine are attractive solvent ligands, since they provide the catalysts with excellent stability and selectivity, and satisfactory activity. The volatility of these ligands is low; the supported liquid phase rhodium catalysts can thus be applied at temperatures up to ∼140°, without severe loss of phosphine by evaporation Above 150° deactivation of the catalysts is observed; this is thought to be due to metalation of the coordinated ligands by the Rh metal.
If you want to learn more about this compound(Tri(naphthalen-1-yl)phosphine)Recommanded Product: 3411-48-1, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(3411-48-1).
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis