Top Picks: new discover of 108-47-4

Because enzymes can increase reaction rates by enormous factors and tend to be very specific, they are the focus of active research. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 108-47-4

Application of 108-47-4, In some cases, the catalyzed mechanism may include additional steps. Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. 108-47-4, Name is 2,4-Dimethylpyridine,introducing its new discovery.

Heat capacities of the six dimethylpyridines between the temperatures 10 K and 445 K and methyl-group rotational barriers in the solid state

Heat capacities and enthalpy increments between the temperatures T = 10 K and 445 K were determined for the six dimethylpyridines by adiabatic calorimetry. (Chemical Abstract registry numbers: 2,3-dimethylpyridine <583-61-9>; 2,4-dimethylpyridine <108-47-4>; 2,5-dimethylpyridine <589-93-5>; 2,6-dimethylpyridine <108-48-5>; 3,4-dimethylpyridine <583-58-4>; and 3,5-dimethylpyridine <591-22-0>.) Triple-point temperatures and enthalpies of fusion are reported for each material, and enthalpy increments and entropies relative to those of the crystals at T -> 0 were derived.Lambda-type phase transitions in the crystals were observed for 2,6-dimethylpyridine and 3,4-dimethylpyridine.A small step or “bump” was observed in the heat-capacity-against-temperature curves for 2,6-dimethylpyridine and 2,3-dimethylpyridine.Barriers to methyl-group rotation in the solid state are estimated for each compound and compared with literature values.

Because enzymes can increase reaction rates by enormous factors and tend to be very specific, they are the focus of active research. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 108-47-4

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis