Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 14389-12-9, is researched, SMILESS is C1(C2=NN=NN2)=CC=NC=C1, Molecular C6H5N5Journal, Article, Acta Crystallographica, Section E: Structure Reports Online called Triaquadichlorido[5-(4-pyridinio)tetrazolato-κN2]cobalt(II) monohydrate, Author is Wang, Bo, the main research direction is crystal structure cobalt pyridinio tetrazolato chloro aqua complex monohydrate; mol structure cobalt pyridiniotetrazolato chloro aqua complex hydrate; hydrogen bond cobalt pyridiniotetrazolato chloro aqua complex monohydrate; pi stacking cobalt pyridiniotetrazolato chloro aqua complex monohydrate; tetrazolato pyridinio cobalt chloro aqua monohydrate crystal mol structure.SDS of cas: 14389-12-9.
Triaquadichloro[5-(4-pyridinio)tetrazolato-κN2]cobalt monohydrate, [CoCl2(C6H5N5)(H2O)3]·H2O, was synthesized by hydrothermal reaction of CoCl2 with 4-(2H-tetrazol-5-yl)pyridine. The CoII cation is coordinated by 2 Cl- ions, 1 N atom from the 5-(4-pyridinio)tetrazolate zwitterion and 3 O atoms from 3 H2O mols. in a distorted octahedral geometry. In the crystal, mols. are linked into a 3-dimensional network by N-H···Cl H bonds and O-H···O/N/Cl H bonds involving both coordinated and uncoordinated H2O mols. Strong π-π stacking is present between parallel pyridinium and tetrazolate rings [centroid-centroid distances = 3.411(2) and 3.436(2) Å]. Crystallog. data are given.
The article 《Triaquadichlorido[5-(4-pyridinio)tetrazolato-κN2]cobalt(II) monohydrate》 also mentions many details about this compound(14389-12-9)SDS of cas: 14389-12-9, you can pay attention to it, because details determine success or failure
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Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis—I. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis