What I Wish Everyone Knew About 136030-00-7

Interested yet? Keep reading other articles of 136030-00-7, you can contact me at any time and look forward to more communication. Category: chiral-nitrogen-ligands.

A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 136030-00-7, Name is (1R,2S)-1-Amino-2,3-dihydro-1H-inden-2-ol, molecular formula is C9H11NO. In an article, author is Okamoto, Kazuhiro,once mentioned of 136030-00-7, Category: chiral-nitrogen-ligands.

Asymmetric Synthesis of 2H-Azirines with a Tetrasubstituted Stereo-center by Enantioselective Ring Contraction of Isoxazoles

Highly strained 2H-azirines with a tetrasubstituted stereocenter were synthesized by the enantioselective isomerization of isoxazoles with a chiral diene-rhodium catalyst system. The effect of ligands and the coordination behavior support the proposed catalytic cycle in which the coordination site is fixed in favor of efficient enantiodiscrimination by a bulky substituent of the ligand. In silico studies also support the existence of a rhodium-imido complex as a key intermediate for enantiodiscrimination.

Interested yet? Keep reading other articles of 136030-00-7, you can contact me at any time and look forward to more communication. Category: chiral-nitrogen-ligands.

Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis