Application of 50893-53-3, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 50893-53-3, Name is 1-Chloroethyl carbonochloridate, SMILES is O=C(Cl)OC(Cl)C, belongs to chiral-nitrogen-ligands compound. In a article, author is Vigano, Marta, introduce new discover of the category.
A chiral ligand accessible in one step: Synthesis of bis-((R)-(+)-bornyl) acenaphthenequinonediimine and of its zinc and nickel complexes
A new neutral chiral nitrogen ligand was obtained in one step from commercially available acenaphthenequinone and (R)-(+)-bornylamine. Use of titanium tetraisopropoxide is the key to obtain good yields of the condensed product. Ring strain in the bicyclic system helps in stabilizing the otherwise unstable Alkyl-BIAN type derivative, but is not enough to render the free ligand indefinitely stable. However, complexes of the ligand with the ZnCl2 and NiBr2 fragment were prepared and are stable. The single crystal X-ray structure of ((R)-(+)-Bornyl-BIAN)NiBr2 has been determined.
Application of 50893-53-3, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 50893-53-3.
Reference:
Chiral nitrogen ligands in late transition metal-catalysed asymmetric synthesis¡ªI. Addressing the problem of ligand lability in rhodium-catalysed hydrosilations,
,Nitrogen-Containing Ligands for Asymmetric Homogeneous and Heterogeneous Catalysis